Introduction

CPP (Chlorinated Polypropylene) is a thermoplastic resin produced through the chlorination modification of polypropylene. By introducing chlorine atoms, CPP gains polar structures that effectively improve the adhesion and film-forming properties of raw polypropylene, leading to widespread applications in inks, coatings, and adhesives. CPP was first developed in the 1960s by Hercules Powder Company in the United States, and was subsequently promoted to global markets by enterprises such as Eastman and Nippon Paper Industries.

Structure & Physical Properties

  • Appearance : White or light yellow granules/powder

  • Polarity : Possesses moderate polarity after chlorination modification, offering compatibility with a wide range of resins

  • Solubility : Soluble in aromatic hydrocarbons, esters, and ketones; insoluble in ethanol and petroleum ether

  • Resistance : Demonstrates water resistance, acid resistance, oil resistance, and light resistance

  • Film-Forming Ability : Transparent, flexible, and resistant to embrittlement/cracking, making it ideal for film applications

Chlorine Content & Classification

CPP is classified into two main types based on chlorine content:

TypeChlorine Content (%)Characteristics & Applications
Low Chlorination20–40%Excellent film-forming properties; suitable for printing inks and primers
High Chlorination63–67%Strong adhesion; suitable for metals and special substrates

Technical Tips | Precautions for Selecting CPP

  • The performance of CPP resin varies depending on chlorine content, molecular weight, and solvent selection.

  • When formulating printing inks or coatings, it is recommended to use ester or aromatic solvents to ensure dissolution stability.

  • JUYEE provides low chlorination CPP products (chlorine content approx. 24–40%) and does not supply high chlorination grades.

  • For further confirmation on compatibility or formulation recommendations, please refer to our CPP product pages.